MALLINCKRODT INC. SCIENCE PRODUCTS DIVISION -- 1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE -- 6810-01-210-0149
=====================  Product Identification  =====================

Product ID:1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE
MSDS Date:03/14/1990
FSC:6810
NIIN:01-210-0149
=== Responsible Party ===
Company Name:MALLINCKRODT INC. SCIENCE PRODUCTS DIVISION
Address:PARIS BYPASS
Box:M
City:PARIS
State:KY
ZIP:40361
Country:US
Info Phone Num:800-354-2050(PRESS 3)/314-982-5000
Emergency Phone Num:800-354-2050/314-539-1600
CAGE:62910
=== Contractor Identification ===
Company Name:MALLINCKRODT SPECIALTY CHEMICALS CO
Address:222 RED SCHOOL LANE
Box:City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Phone:908-859-2151
CAGE:62910

=============  Composition/Information on Ingredients  =============

Ingred Name:1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113) (SARA
    313)
CAS:76-13-1
RTECS #:KJ4000000
Fraction by Wt: 100%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1000 PPM
ACGIH TLV:1000PPM/1250STEL9495
Ozone Depleting Chemical:1

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:ORAL LD50 (RAT) IS 43000 MG/KG
Routes of Entry: Inhalation:YES  Skin:NO  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:ACUTE:ANESTHETIC IF INHALED.INHALATION
    OF VERY HIGH CONCENTRATIONS MAY CAUSE ASPHYXIATION,CARDIAC
    ARRHYTHMIAS.CONTACT MAY CAUSE SKIN IRRITATION/DEFATTING;EYE
    IRRITATION/POSSIBLE EYE DAMAGE.NO INFORMAT ION FOUND ON
    INGESTION,MAY PRODUCE SIMILAR TO
    INHALATION.CHRONIC:PROLONGED/REPEATED EXPOSURE MAY CAUSE
    DERMATITIS.
Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1%
    OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN.
Effects of Overexposure:INHALED-INCOORDINATION, CARDIAC ARRHYTHMIAS,
    DROWSINESS, EXCITEMENT. EYES-REDNESS, TEARING, DISCOMFORT.
    SKIN-DEFATTING, REDNESS, DISCOMFORT. INGESTED-NO INFORMATION FOUND.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN OR
    EYE DISORDERS OR IMPAIRED RESPIRATORY FUNCTION MAY BE MORE
    SUSCEPTIBLE TO THE EFFECTS OF THIS SUBSTANCE.

=======================  First Aid Measures  =======================

First Aid:IN ALL CASES CALL A PHYSICIAN. EYES-IMMEDIATELY FLUSH WITH
    WATER FOR 15 MINUTES. SKIN-REMOVE CONTAMINATED CLOTHES. WASH WITH
    MILD SOAP & WATER. INHALED-REMOVE TO FRESH AIR. ADMINISTER OXYGEN
    OR ARTIFI CIAL RESPIRATION AS NEEDED. INGESTED-IFCONSCIOUS, INDUCE
    VOMITING IMMEDIATELY BY GIVING WATER OR MILK & STICK FINGER DOWN
    THROAT. NOTE TO DR: DO NOT USE EPINEPHRINE!

=====================  Fire Fighting Measures  =====================

Flash Point:NON-FLAMMABLE
Extinguishing Media:USE MEDIA APPROPRIATE FOR SURROUNDING FIRE.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS IN
    PRESSURE DEMAND OR POSITIVE PRESSURE MODE AND FULL PROTECTIVE GEAR.
    COOL FIRE EXPOSED CONTAINERS WITH WATER.
Unusual Fire/Explosion Hazard:NOT CONSIDERED TO BE AN EXPLOSION HAZARD.

==================  Accidental Release Measures  ==================

Spill Release Procedures:VENTILATE AND EVACUATE AREA. CLEAN-UP
    PERSONNEL REQUIRE CLOTHING AND RESPIRATORY PROTECTION. ELIMINATE
    ALL SOURCES OF IGNITION. CONTAIN & RECOVER. ABSORB WITH INERT
    MATERIAL AND PLACE IN CONTAINER FOR  DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:KEEP IN A TIGHTLY CLOSED CONTAINER.
    STORE IN A COOL, DRY, WELL-VENTILATED PLACE AWAY FROM SOURCES OF
    IGNITION. PROTECT AGAINST PHYSICAL DAMAGE.
Other Precautions:ISOLATE FROM INCOMPATIBLE MATERIALS. DO NOT WEAR
    CONTACT LENSES WHEN USING THIS PRODUCT.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:IF ENGINEERING CONTROLS FAIL OR NON-ROUTINE USE
    OR AN EMERGENCY OCCURS; WEAR AN MSHA/NIOSH APPROVED RESPIRATOR OR
    AN AIR-SUPPLIED RESPIRATOR OR SCBA, AS REQUIRED. USE IN ACCORDANCE
    WITH 29 CFR 1910.13 4 AND MANUFACTURER'S RECOMMENDATIONS.
Ventilation:USE ADEQUATE MECHANICAL VENTILATION OR LOCAL EXHAUST TO
    MAINTAIN EXPOSURE BELOW TLV(S).
Protective Gloves:NITRILE, PVA.
Eye Protection:SAFETY GLASSES/CHEMICAL SPLASH GOGGLES.
Other Protective Equipment:WEAR CLEAN, BODY COVERING CLOTHING.
    DLA-HMIS: EYE WASH.
Work Hygienic Practices:WASH HANDS AFTER HANDLING AND BEFORE EATING,
    DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE.
Supplemental Safety and Health
ENVIRONMENTAL DATA: SARA 311/312-ACUTE, CHRONIC; SARA
    313-1,12-TRICHLORO-1,2,2-TRIFLUOROETHANE, CAS# 70-13-1, 100%; SARA
    302-RQ/NO, TPQ/NO; CERCLA 103/NO; RCRA 261.33/NO.

==================  Physical/Chemical Properties  ==================

HCC:N1
Boiling Pt:B.P. Text:117F,47C
Melt/Freeze Pt:M.P/F.P Text:-33F,-36C
Vapor Pres:334
Vapor Density:6.5
Spec Gravity:1.57
Evaporation Rate & Reference:0.3 (CCL4=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR, COLORLESS LIQUID; SLIGHT ETHEREAL ODOR.

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
ALKALI OR ALKALINE EARTH METALS (POWDERED ALUMINUM, ZINC, BERYLLIUM,
    MAGNESIUM), HEAT AND OPEN FLAME.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:TOXIC VAPORS AND GASES SUCH AS HALOGEN
    ACIDS, HALOGENS AND CARBONYL ALKALIES MAY BE RELEASED IF INVOLVED
    IN FIRE.
Conditions to Avoid Polymerization:HTIS PRODUCT DOES NOT POLYMERIZE.

====================  Disposal Considerations  ====================

Waste Disposal Methods:WASTE MAY BE CONTAINERIZED AND DISPOSED IN A
    RCRA APPROVED FACILITY. DO NOT FLUSH TO SEWER!

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