MALLINCKRODT INC. SCIENCE PRODUCTS DIVISION -- AMMONIUM SULFIDE SOLUTION -- 6810-00D005101
===================== Product Identification ===================== Product ID:AMMONIUM SULFIDE SOLUTION MSDS Date:07/09/1987 FSC:6810 NIIN:00D005101 === Responsible Party === Company Name:MALLINCKRODT INC. SCIENCE PRODUCTS DIVISION Address:PARIS BYPASS Box:M City:PARIS State:KY ZIP:40361 Country:US Info Phone Num:800-354-2050(PRESS 3)/314-982-5000 Emergency Phone Num:800-354-2050/314-982-5000 CAGE:62910 === Contractor Identification === Company Name:FREY SCIENTIFIC Address:100 PARAGON PARKWAY Box:City:MANSFIELD State:OH ZIP:44905 Country:US Phone:419-589-1900 CAGE:6U218 Company Name:MALLINCKRODT SPECIALTY CHEMICALS CO Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:908-859-2151 CAGE:62910 ============= Composition/Information on Ingredients ============= Ingred Name:AMMONIUM SULFIDE (CERCLA) CAS:12135-76-1 RTECS #:BS4920000 Fraction by Wt: 20-24% Other REC Limits:NONE RECOMMENDED EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:NO LD50 INFO FOUND Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INHAL:IRRIT MUC MEMB.CONCEN OF HYDROGEN SULFIDE >50PPM CAUSE HEAD,INSOMNIA,NAU,SORE THROAT,DIZZ,DROWS,PULM EDEMA.INGEST:CORR TO GI TRACT THRU LIBERATION OF HYDROGEN SULFIDE.VOMIT,HEAD,CYANOSIS,RESP DE PRESS,BLOOD PRESSURE FALL,UNCONSC,TREMORS,CONVULS,DEATH.SKIN/EYE:IRRIT,REDNESS,PAIN.CHRO NIC:DMG EXPO TISSUES. Effects of Overexposure:IRRIT MUC MEMBRANCE/EYE/SKIN. HEADACHE, INSOMNIA, NAUSEA, SORE THROAT, DIZZINESS, DROWSINESS, PULMONARY EDEMA. CORRO TO GI TRACT, VOMIT, CYANOSIS, RESP DEPRESSION, BLOOD PRESSRUE FALL, UNCONSC, TREMOR S, CONVULSIONS, DEATH. EYE/SKIN:REDNESS, PAIN. COUGHING, SHORTNESS OF BREATH. Medical Cond Aggravated by Exposure:NO INFORMATION FOUND. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESH AIR.ANY BREATH DIFFI GET MED ATTN. INGEST:INDUCE VOMIT IMMED BY GIVING 2 GLASSES OF WATER & STICKING FINGER DOWN THROAT.NEVER GIVE ANYTHING BY MOUTH IF UNCONSC.CALL PHYSICIAN IMM ED. SKIN:REMOVE ANY CONTAMIN CLOTH.WSH W/PLENTY OF WATER FOR @LEAST 15MINS.IRRIT DEVELOPS GET MED ATTN. EYE:WASH W/PLENTY OF WATER FOR @LEAST 15MINS.IRRIT DEVELOPS GET MED ATTN. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:140F,60C Extinguishing Media:DO NOT USE CARBON DIOXIDE AS FLAMM TOXIC HYDROGEN SULFIDE GAS CAN BE GENERATED.ALCOHOL FOAM OR DRY CHEM MAY BE USED. Fire Fighting Procedures:APPLY WATER FRM FAR DISTANCE AS POSSIBLE.USE WATER IN FLOODING QUANT AS FOG:SOLID STREAMS OF WATER MAY BE INEFFECTIVE TO KNOCK DOWN VAP.WEAR FULL PROT (SUPPLEM) Unusual Fire/Explosion Hazard:NOT CONSIDERED EXPLO HAZ BUT CONTACT W/POWERFUL OXIDIZERS MAY CAUSE EXPLO. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA. CLEAN-UP PERSONNEL REQUIRE PORTECTIVE CLOTHING. CONTAIN & RECOVER LIQ WHEN POSSIBLE.LG:ABSORB W/VERMICULITE,DRY SAND,EARY,OR SIMILAR MATL FOR DISPO AS HAZ WASTE IN RCRA APPROVED FACILI TY. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:PROTECT AGAINST PHSYICIAL DMG.OUTSIDE/DETACHED STORAGE PREFERRED.INSIDE STORAGE SHOULD BE STD FLAMM LIQ STORAGE RM/CABINET. Other Precautions:REF:ACGIH DOC "INDUSTRIAL VENTI:MANUAL OF RECOMMENDED PRAC".CONTACT LENSES SHOULD NOT BE WORN WHEN WORKING W/MATL.SEPARATE FROM ACIDS & OXIDIZING MATLS.STORAGE & USE AREAS SHOULD BE NO SMOKING AREAS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF TLV EXCEEDED DUST/MIST RESP W/CHEM GOGGLES MAY BE WORN IN GENERAL UP TO 10X TLV.CONSULT RESPIRATOR SUPPLIER FOR LIMITATIONS.ALTERNATIVELY SUPPLIED AIR FULL FACEPIECE RESP OR AIRLINED HOOD MAY BE WO RN. Ventilation:SYS OF LOC &/OR GEN EXHAU RECOMMENDED TO KEEP WORKER EXPO BEL AEL.LOC EXHAU VENTI PREF-CAN CNTRL EMISSIONS OF (SUPPLEME) Protective Gloves:PROTECTIVE GLOVES. Eye Protection:CHEM SAF GOGGLES. Other Protective Equipment:CLEAN BODY-COVERING CLOTHING.MAINTAIN EYE WASH FOUNTAIN & QUICK-DRENCH FACILITIES IN WORKAREA. Work Hygienic Practices:WASH CONTAMIN CLOTHH BEF REUSE. WASH AFT HNDLG. Supplemental Safety and Health FIREFIGHTING:CLOTH & NIOSH-APPROVED SCBA W/FULL FCPIECE OPERATED IN PRESSURE DEMAND/OTHER POSITIVE PRESSURE MODE. VENTI:CONTAMINANT @SOURCE,PREVENTING DISPERSION OF INTO GEN WORKAREA. ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:DECOMPOSES Melt/Freeze Pt:M.P/F.P Text:NO INFO Vapor Pres:NO INFO Vapor Density:NO INFO Evaporation Rate & Reference:NO INFO FOUND Solubility in Water:INFINITE Appearance and Odor:CLEAR, YELLOW LIQUID, STRONG CHARACTERISTIC ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CONTACT W/ACIDS MAY EVOLVE HYDROGEN SULFIDE. OXIDIZERS, ZINC. Stability Condition to Avoid:MAY LOSE INTEGRITY W/AGE:MATL SLOWLY PRODUCES HYDROGEN SULFIDE & AMMONIA IN PRESENCE OF MOISTURE. Hazardous Decomposition Products:EMITS TOXIC FUMES OF SULFUR OXIDES, NITRIC OXIDES, AND AMMONIA WHEN HEATED TO DECOMPOSITION. ==================== Disposal Considerations ==================== Waste Disposal Methods:DO NOT FLUSH TO SEWER.RQ:100LBS.ENSURE COMPLIANCE W/LOCAL, STATE AND FEDERAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.